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Title: Revision of the Phytochemistry of Eremophila sturtii and E. mitchellii
Contributor(s): Sadgrove, Nicholas J  (author); Klepp, Julian  (author); Legendre, Sarah V A-M  (author); Lyddiard, Dane  (author); Sumby, Christopher J (author); Greatrex, Ben W  (author)orcid 
Publication Date: 2018-01-24
DOI: 10.1021/acs.jnatprod.7b00616
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Abstract: Eremophila sturtii and E. mitchellii are found in the arid and temperate regions of Australia and, because of their similar appearances, are often confused. Previous phytochemical investigations have described mitchellene sesquiterpenes (1–5) reported from E. mitchellii but are here demonstrated to be from E. sturtii. A previous study that described serrulatic acids (16 and 17) from a species reported as E. sturtii actually used E. mitchellii. In addition, two new C–15 modified analogues, mitchellenes F (14) and G (15), were isolated from E. sturtii. The absolute configuration of 14 was determined with the first X-ray structure of a compound with the mitchellene skeleton.
Publication Type: Journal Article
Source of Publication: Journal of Natural Products, 81(2), p. 405-409
Publisher: American Chemical Society
Place of Publication: United States of America
ISSN: 0163-3864
Field of Research (FOR): 030502 Natural Products Chemistry
060310 Plant Systematics and Taxonomy
030503 Organic Chemical Synthesis
Socio-Economic Objective (SEO): 970103 Expanding Knowledge in the Chemical Sciences
970106 Expanding Knowledge in the Biological Sciences
Peer Reviewed: Yes
HERDC Category Description: C1 Refereed Article in a Scholarly Journal
Appears in Collections:Journal Article
School of Rural Medicine
School of Science and Technology

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