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Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/58468
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dc.contributor.authorLegendre, Sarah V A Men
dc.contributor.authorSumby, Christopher Jen
dc.contributor.authorKarton, Amiren
dc.contributor.authorGreatrex, Ben Wen
dc.date.accessioned2024-04-19T01:56:39Z-
dc.date.available2024-04-19T01:56:39Z-
dc.date.issued2023-08-18-
dc.identifier.citationThe Journal of Organic Chemistry, v.88, p. 11444-11449en
dc.identifier.issn1520-6904en
dc.identifier.issn0022-3263en
dc.identifier.urihttps://hdl.handle.net/1959.11/58468-
dc.description.abstract<p>Bifunctional thiourea/amine organocatalysts have been used for the desymmetrization of <i>meso</i>-endoperoxides using the Kornblum−DeLaMare reaction, giving 4-hydroxyketones in 78−98% yields with ≤98:2 enantioselectivity. The influence of the catalyst structure, solvent, and temperature was examined. The most promising catalyst was applied to the kinetic resolution of racemic endoperoxides to give enantioenriched materials (≤99:1 er).</p>en
dc.languageenen
dc.publisherAmerican Chemical Societyen
dc.relation.ispartofThe Journal of Organic Chemistryen
dc.titleDesymmetrization and Kinetic Resolution of Endoperoxides Using a Bifunctional Organocatalysten
dc.typeJournal Articleen
dc.identifier.doi10.1021/acs.joc.3c00278en
local.contributor.firstnameSarah V A Men
local.contributor.firstnameChristopher Jen
local.contributor.firstnameAmiren
local.contributor.firstnameBen Wen
local.profile.schoolSchool of Science and Technologyen
local.profile.schoolSchool of Science and Technologyen
local.profile.schoolSchool of Rural Medicineen
local.profile.emailslegend2@une.edu.auen
local.profile.emailakarton@une.edu.auen
local.profile.emailbgreatre@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.publisher.placeUnited States of Americaen
local.format.startpage11444en
local.format.endpage11449en
local.peerreviewedYesen
local.identifier.volume88en
local.contributor.lastnameLegendreen
local.contributor.lastnameSumbyen
local.contributor.lastnameKartonen
local.contributor.lastnameGreatrexen
dc.identifier.staffune-id:slegend2en
dc.identifier.staffune-id:akartonen
dc.identifier.staffune-id:bgreatreen
local.profile.orcid0000-0002-7981-508Xen
local.profile.orcid0000-0002-0356-4966en
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.identifier.unepublicationidune:1959.11/58468en
local.date.onlineversion2023-08-08-
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
local.title.maintitleDesymmetrization and Kinetic Resolution of Endoperoxides Using a Bifunctional Organocatalysten
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.search.authorLegendre, Sarah V A Men
local.search.authorSumby, Christopher Jen
local.search.authorKarton, Amiren
local.search.authorGreatrex, Ben Wen
local.open.fileurlhttps://rune.une.edu.au/web/retrieve/d715f5e3-8c00-4d97-a776-06722d5d736ben
local.uneassociationYesen
local.atsiresearchNoen
local.sensitive.culturalNoen
local.year.available2023en
local.year.published2023en
local.fileurl.openhttps://rune.une.edu.au/web/retrieve/d715f5e3-8c00-4d97-a776-06722d5d736ben
local.fileurl.closedpublishedhttps://rune.une.edu.au/web/retrieve/d715f5e3-8c00-4d97-a776-06722d5d736ben
local.subject.for20203407 Theoretical and computational chemistryen
local.profile.affiliationtypeUNE Affiliationen
local.profile.affiliationtypeExternal Affiliationen
local.profile.affiliationtypeUNE Affiliationen
local.profile.affiliationtypeUNE Affiliationen
local.date.moved2024-04-19en
Appears in Collections:Journal Article
School of Rural Medicine
School of Science and Technology
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