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Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/16535
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dc.contributor.authorStockton, Kieranen
dc.contributor.authorGlover, Stephenen
dc.contributor.authorGreatrex, Benen
dc.date.accessioned2015-01-22T16:39:00Z-
dc.date.issued2015-
dc.identifier.citationSynlett, 26(1), p. 111-115en
dc.identifier.issn1437-2096en
dc.identifier.issn0936-5214en
dc.identifier.urihttps://hdl.handle.net/1959.11/16535-
dc.description.abstractProtected inosose 2-O-mesylates generate oxyallyl systems by elimination of the mesylate group after enolization. The reaction is promoted by weak bases such as triethylamine and azide, and the oxyallyl systems are then trapped by nucleophilic alcohols or azide. Computations using DFT/B3LYP confirm that the singlet planar oxyallyl is stabilized by the exocyclic alkoxy group.en
dc.languageenen
dc.publisherGeorg Thieme Verlagen
dc.relation.ispartofSynletten
dc.titleNucleophilic Trapping of Alkoxy-Stabilized Oxyallyl Systems Generated from Inosose 2-O-Mesylatesen
dc.typeJournal Articleen
dc.identifier.doi10.1055/s-0034-1379490en
dcterms.accessRightsGolden
dc.subject.keywordsNatural Products Chemistryen
dc.subject.keywordsOrganic Chemical Synthesisen
dc.subject.keywordsPhysical Organic Chemistryen
local.contributor.firstnameKieranen
local.contributor.firstnameStephenen
local.contributor.firstnameBenen
local.subject.for2008030503 Organic Chemical Synthesisen
local.subject.for2008030502 Natural Products Chemistryen
local.subject.for2008030505 Physical Organic Chemistryen
local.subject.seo2008970103 Expanding Knowledge in the Chemical Sciencesen
local.subject.seo2008860803 Human Pharmaceutical Treatments (e.g. Antibiotics)en
local.profile.schoolIT Voice Systemsen
local.profile.schoolSchool of Science and Technologyen
local.profile.schoolSchool of Rural Medicineen
local.profile.emailkstockt2@une.edu.auen
local.profile.emailsglover@une.edu.auen
local.profile.emailbgreatre@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.identifier.epublicationsrecordune-20150121-104612en
local.publisher.placeGermanyen
local.format.startpage111en
local.format.endpage115en
local.identifier.scopusid84910143966en
local.peerreviewedYesen
local.identifier.volume26en
local.identifier.issue1en
local.access.fulltextYesen
local.contributor.lastnameStocktonen
local.contributor.lastnameGloveren
local.contributor.lastnameGreatrexen
dc.identifier.staffune-id:kstockt2en
dc.identifier.staffune-id:sgloveren
dc.identifier.staffune-id:bgreatreen
local.profile.orcid0000-0002-9344-8669en
local.profile.orcid0000-0002-0356-4966en
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.identifier.unepublicationidune:16772en
local.identifier.handlehttps://hdl.handle.net/1959.11/16535en
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
local.title.maintitleNucleophilic Trapping of Alkoxy-Stabilized Oxyallyl Systems Generated from Inosose 2-O-Mesylatesen
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.search.authorStockton, Kieranen
local.search.authorGlover, Stephenen
local.search.authorGreatrex, Benen
local.uneassociationUnknownen
local.identifier.wosid000346492100021en
local.year.published2015-
local.subject.for2020340503 Organic chemical synthesisen
local.subject.for2020340505 Physical organic chemistryen
local.subject.for2020340502 Natural products and bioactive compoundsen
local.subject.seo2020280105 Expanding knowledge in the chemical sciencesen
local.subject.seo2020240803 Human pharmaceutical treatmentsen
Appears in Collections:Journal Article
School of Rural Medicine
School of Science and Technology
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