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https://hdl.handle.net/1959.11/8274| Title: | Highly-oxidised, sulfur-rich, mixed-valence vanadium(IV/V) complexes | Contributor(s): | Taylor, Michelle K (author); Evans, DJ (author); Young, CG (author) | Publication Date: | 2006 | DOI: | 10.1039/B610036H | Handle Link: | https://hdl.handle.net/1959.11/8274 | Abstract: | The reactions of [V₂(μ-S₂)₂(S₂CNR₂)₄] (R = alkyl) with NOBF₄ produce highly-oxidised, sulfur-rich, V(IV/V) complexes, [V2(μ-S₂)₂(S₂CNR₂)₄]BF₄, that exhibit 15-line EPR spectra and structures consistent with Class III mixed-valence behaviour. | Publication Type: | Journal Article | Source of Publication: | Chemical Communications (40), p. 4245-4246 | Publisher: | Royal Society of Chemistry | Place of Publication: | United Kingdom | ISSN: | 1364-548X 1359-7345 |
Fields of Research (FoR) 2008: | 030207 Transition Metal Chemistry | Socio-Economic Objective (SEO) 2008: | 970103 Expanding Knowledge in the Chemical Sciences | Peer Reviewed: | Yes | HERDC Category Description: | C1 Refereed Article in a Scholarly Journal |
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| Appears in Collections: | Journal Article School of Science and Technology |
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