Enamines from the biomass derivative Cyrene and reactions with isocyanates and ketenes

Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/58814

Title:	Enamines from the biomass derivative Cyrene and reactions with isocyanates and ketenes
Contributor(s):	Podversnik, Harald (author); Curtis, Ian (author); Pieterse, Elsie (author); Jevric, Martyn (author); Sumby, Christopher J (author); W Greatrex, Ben (author)
Publication Date:	2023-10-06
DOI:	10.1016/j.tetlet.2023.154755
Handle Link:	https://hdl.handle.net/1959.11/58814
Abstract:	To extend the chemical space accessible from the biomass-derived platform chemical Cyrene, enamines have been prepared and their reactions with selected electrophiles have been examined. The crystalline enamines prepared from morpholine (89% yield) and piperidine (79% yield) were stable and showed excellent reactivity with isocyanates, isothiocyanates and ketenes to give amides, thioamides or cyclobutanones, respectively.
Publication Type:	Journal Article
Source of Publication:	Tetrahedron Letters, v.129
Publisher:	Elsevier Ltd
Place of Publication:	United Kingdom
ISSN:	1873-3581 0040-4039
Fields of Research (FoR) 2020:	3405 Organic chemistry
Socio-Economic Objective (SEO) 2020:	tbd
Peer Reviewed:	Yes
HERDC Category Description:	C1 Refereed Article in a Scholarly Journal
Appears in Collections:	Journal Article School of Rural Medicine

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