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Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/52104
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dc.contributor.authorYang, Qien
dc.contributor.authorLi, Liangen
dc.contributor.authorHussain, Tanveeren
dc.contributor.authorWang, Donghongen
dc.contributor.authorHui, Lanen
dc.contributor.authorGuo, Yingen
dc.contributor.authorLiang, Guojinen
dc.contributor.authorLi, Xinliangen
dc.contributor.authorChen, Zeen
dc.contributor.authorHuang, Zhaodongen
dc.contributor.authorLi, Yongjunen
dc.contributor.authorXue, Yuruien
dc.contributor.authorZuo, Zichengen
dc.contributor.authorQiu, Jieshanen
dc.contributor.authorLi, Yuliangen
dc.contributor.authorZhi, Chunyien
dc.date.accessioned2022-05-12T01:51:03Z-
dc.date.available2022-05-12T01:51:03Z-
dc.date.issued2022-02-01-
dc.identifier.citationAngewandte Chemie, 134(6), p. 1-9en
dc.identifier.issn1521-3757en
dc.identifier.issn0044-8249en
dc.identifier.urihttps://hdl.handle.net/1959.11/52104-
dc.description.abstract<p><i>Zn dendrite issue was intensively studied via tuning zinc ion flux. pH change seriously influences dendrite formation, while its importance has not been revealed. Here, we construct a N-modification graphdiyne interface (NGI) to stabilize pH by mediating hydrated zinc ion desolvation. Operando pH detection reveals pH stabilization by NGI. This works with pores in NGI to achieve dendrite-free Zn deposition and an increased symmetric cell life span by 116 times. Experimental and theoretical result so we pH stabilization to desolvation with a reduced activation energy achieved by electron transfer from solvation sheath to N atom. The efficient desolvation ensures that electron directly transfers from substrate to Zn<sup>2+</sup>(rather than the coordinated H<sub>2</sub>O), avoiding O-H bond splitting. Hence, Zn-V<sub>6</sub>O<sub>13</sub> battery achieves a long life span at 20.65 mA cm<sup>-2</sup> and 1.07 mAh cm<sup>-2</sup>.This work reveals the significance of interface pH and provides a new approach to address Zn dendrite issue.</i></p>en
dc.languageenen
dc.publisherWiley-VCH Verlag GmbH & Co KGaAen
dc.relation.ispartofAngewandte Chemieen
dc.titleStabilizing Interface pH by N‐Modified Graphdiyne for Dendrite‐Free and High‐Rate Aqueous Zn‐Ion Batteriesen
dc.typeJournal Articleen
dc.identifier.doi10.1002/ange.202112304en
local.contributor.firstnameQien
local.contributor.firstnameLiangen
local.contributor.firstnameTanveeren
local.contributor.firstnameDonghongen
local.contributor.firstnameLanen
local.contributor.firstnameYingen
local.contributor.firstnameGuojinen
local.contributor.firstnameXinliangen
local.contributor.firstnameZeen
local.contributor.firstnameZhaodongen
local.contributor.firstnameYongjunen
local.contributor.firstnameYuruien
local.contributor.firstnameZichengen
local.contributor.firstnameJieshanen
local.contributor.firstnameYuliangen
local.contributor.firstnameChunyien
local.profile.schoolSchool of Science and Technologyen
local.profile.emailthussai3@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.publisher.placeGermanyen
local.identifier.runningnumbere202112304en
local.format.startpage1en
local.format.endpage9en
local.peerreviewedYesen
local.identifier.volume134en
local.identifier.issue6en
local.contributor.lastnameYangen
local.contributor.lastnameLien
local.contributor.lastnameHussainen
local.contributor.lastnameWangen
local.contributor.lastnameHuien
local.contributor.lastnameGuoen
local.contributor.lastnameLiangen
local.contributor.lastnameLien
local.contributor.lastnameChenen
local.contributor.lastnameHuangen
local.contributor.lastnameLien
local.contributor.lastnameXueen
local.contributor.lastnameZuoen
local.contributor.lastnameQiuen
local.contributor.lastnameLien
local.contributor.lastnameZhien
dc.identifier.staffune-id:thussai3en
local.profile.orcid0000-0003-1973-4584en
local.profile.roleauthoren
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local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
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local.identifier.unepublicationidune:1959.11/52104en
local.date.onlineversion2021-11-19-
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
local.title.maintitleStabilizing Interface pH by N‐Modified Graphdiyne for Dendrite‐Free and High‐Rate Aqueous Zn‐Ion Batteriesen
local.relation.fundingsourcenoteThis research was supported by GRF Scheme under Project CityU 11305218.en
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.search.authorYang, Qien
local.search.authorLi, Liangen
local.search.authorHussain, Tanveeren
local.search.authorWang, Donghongen
local.search.authorHui, Lanen
local.search.authorGuo, Yingen
local.search.authorLiang, Guojinen
local.search.authorLi, Xinliangen
local.search.authorChen, Zeen
local.search.authorHuang, Zhaodongen
local.search.authorLi, Yongjunen
local.search.authorXue, Yuruien
local.search.authorZuo, Zichengen
local.search.authorQiu, Jieshanen
local.search.authorLi, Yuliangen
local.search.authorZhi, Chunyien
local.uneassociationNoen
local.atsiresearchNoen
local.sensitive.culturalNoen
local.identifier.wosid000731800000001en
local.year.available2021en
local.year.published2022en
local.fileurl.closedpublishedhttps://rune.une.edu.au/web/retrieve/265cdf28-a228-4b85-a2f7-5b97dba1fa01en
local.subject.for2020400404 Electrochemical energy storage and conversionen
local.subject.for2020400403 Chemical engineering designen
local.subject.for2020400499 Chemical engineering not elsewhere classifieden
local.subject.seo2020170301 Battery storageen
local.subject.seo2020170803 Hydro-electric energyen
local.subject.seo2020170899 Renewable energy not elsewhere classifieden
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School of Science and Technology
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