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Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/47456
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dc.contributor.authorThenarukandiyil, Ranjeeshen
dc.contributor.authorPaenurk, Enoen
dc.contributor.authorWong, Anthonyen
dc.contributor.authorFridman, Nataliaen
dc.contributor.authorKarton, Amiren
dc.contributor.authorCarmieli, Raananen
dc.contributor.authorMénard, Gabrielen
dc.contributor.authorGershoni-Poranne, Renanaen
dc.contributor.authorde Ruiter, Grahamen
dc.date.accessioned2022-03-07T04:25:40Z-
dc.date.available2022-03-07T04:25:40Z-
dc.date.issued2021-12-06-
dc.identifier.citationInorganic Chemistry, 60(23), p. 18296-18306en
dc.identifier.issn1520-510Xen
dc.identifier.issn0020-1669en
dc.identifier.urihttps://hdl.handle.net/1959.11/47456-
dc.description.abstract<p>Metal-ligand cooperation is an important aspect in earth-abundant metal catalysis. Utilizing ligands as electron reservoirs to supplement the redox chemistry of the metal has resulted in many new exciting discoveries. Here, we demonstrate that iron bipyridine-diimine (BDI) complexes exhibit an extensive electron-transfer series that spans a total of five oxidation states, ranging from the trication [Fe(BDI)]<sup>3+</sup> to the monoanion [Fe(BDI]<sup>-1</sup>. Structural characterization by X-ray crystallography revealed the multifaceted redox noninnocence of the BDI ligand, while spectroscopic (e.g., <sup>57</sup>Fe Mössbauer and EPR spectroscopy) and computational studies were employed to elucidate the electronic structure of the isolated complexes, which are further discussed in this report.</p>en
dc.languageenen
dc.publisherAmerican Chemical Societyen
dc.relation.ispartofInorganic Chemistryen
dc.rightsAttribution 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.titleExtensive Redox Non-Innocence in Iron Bipyridine-Diimine Complexes: a Combined Spectroscopic and Computational Studyen
dc.typeJournal Articleen
dc.identifier.doi10.1021/acs.inorgchem.1c02925en
dc.identifier.pmid34787414en
dcterms.accessRightsGolden
local.contributor.firstnameRanjeeshen
local.contributor.firstnameEnoen
local.contributor.firstnameAnthonyen
local.contributor.firstnameNataliaen
local.contributor.firstnameAmiren
local.contributor.firstnameRaananen
local.contributor.firstnameGabrielen
local.contributor.firstnameRenanaen
local.contributor.firstnameGrahamen
local.relation.isfundedbyARCen
local.profile.schoolSchool of Science and Technologyen
local.profile.emailakarton@une.edu.auen
local.output.categoryC1en
local.grant.numberFT170100373en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.publisher.placeUnited States of Americaen
local.format.startpage18296en
local.format.endpage18306en
local.identifier.scopusid85119955608en
local.peerreviewedYesen
local.identifier.volume60en
local.identifier.issue23en
local.title.subtitlea Combined Spectroscopic and Computational Studyen
local.access.fulltextYesen
local.contributor.lastnameThenarukandiyilen
local.contributor.lastnamePaenurken
local.contributor.lastnameWongen
local.contributor.lastnameFridmanen
local.contributor.lastnameKartonen
local.contributor.lastnameCarmielien
local.contributor.lastnameMénarden
local.contributor.lastnameGershoni-Poranneen
local.contributor.lastnamede Ruiteren
dc.identifier.staffune-id:akartonen
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local.identifier.unepublicationidune:1959.11/47456en
local.date.onlineversion2021-11-17-
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
local.title.maintitleExtensive Redox Non-Innocence in Iron Bipyridine-Diimine Complexesen
local.relation.fundingsourcenoteAzrieli Foundation and the Ministry of Energy (contract #219-11-130) and the Taub Foundationen
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.relation.grantdescriptionARC/FT170100373en
local.search.authorThenarukandiyil, Ranjeeshen
local.search.authorPaenurk, Enoen
local.search.authorWong, Anthonyen
local.search.authorFridman, Nataliaen
local.search.authorKarton, Amiren
local.search.authorCarmieli, Raananen
local.search.authorMénard, Gabrielen
local.search.authorGershoni-Poranne, Renanaen
local.search.authorde Ruiter, Grahamen
local.uneassociationNoen
local.atsiresearchNoen
local.sensitive.culturalNoen
local.identifier.wosid000753441100090en
local.year.available2021en
local.year.published2021en
local.fileurl.closedpublishedhttps://rune.une.edu.au/web/retrieve/c6e9e055-61b6-4f43-8ae2-536239cf4a2aen
local.subject.for2020340701 Computational chemistryen
local.subject.for2020340704 Theoretical quantum chemistryen
local.subject.for2020340799 Theoretical and computational chemistry not elsewhere classifieden
local.subject.seo2020280105 Expanding knowledge in the chemical sciencesen
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