Please use this identifier to cite or link to this item:
https://hdl.handle.net/1959.11/13024
Title: | Quasi-block copolymer libraries on demand 'via' sequential RAFT polymerization in an automated parallel synthesizer | Contributor(s): | Guerrero-Sanchez, Carlos (author); O'Brien, Lisa (author); Brackley, Colin (author); Keddie, Daniel (author); Saubern, Simon (author); Chiefari, John (author) | Publication Date: | 2013 | DOI: | 10.1039/c3py21135e | Handle Link: | https://hdl.handle.net/1959.11/13024 | Abstract: | A convenient synthetic method for the systematic preparation of quasi-diblock copolymer libraries utilizing a sequential RAFT polymerization strategy is described. This method utilizes a parallel synthesizer and allows the unattended and fully automated synthesis of this type of library in a short period of time. The materials obtained in this investigation have shown properties very similar to those expected in "pure" diblock copolymers as determined by differential scanning calorimetry. The described method can be a useful and less expensive alternative for the rapid preparation and screening of block copolymer libraries. | Publication Type: | Journal Article | Source of Publication: | Polymer Chemistry, 4(6), p. 1857-1862 | Publisher: | Royal Society of Chemistry | Place of Publication: | United Kingdom | ISSN: | 1759-9962 1759-9954 |
Fields of Research (FoR) 2008: | 030306 Synthesis of Materials 030305 Polymerisation Mechanisms 030501 Free Radical Chemistry |
Fields of Research (FoR) 2020: | 340207 Metal organic frameworks 340306 Polymerisation mechanisms 340501 Free radical chemistry |
Socio-Economic Objective (SEO) 2008: | 970103 Expanding Knowledge in the Chemical Sciences | Socio-Economic Objective (SEO) 2020: | 280105 Expanding knowledge in the chemical sciences | Peer Reviewed: | Yes | HERDC Category Description: | C1 Refereed Article in a Scholarly Journal |
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Appears in Collections: | Journal Article |
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