Phrygian Gordion was the political center of an influential Iron Age polity that extended across west central Anatolia during the first half of the 1st millennium BC. Though the borders of this polity remain vague a characteristic of the Phrygian 'footprint' is the distribution of highly distinctive ceramics. The extent to which Gordion potters were the originators of these wares remains uncertain. In this paper we use Neutron Activation Analysis (NAA) to establish the local signature of predominantly Iron Age ceramics for this site by combining samples from several decades of excavation with an extensive regional sediment sequence. We also compare previous NAA work at Gordion to suggest that the formative stages of the Phrygian state appears to have involved a more extensive network of non-local specialist producers than previously thought.

The island of Cyprus was a major producer of copper and stood at the heart of east Mediterranean trade networks during the Late Bronze Age. It may also have been the source of the Red Lustrous Wheelmade Ware that has been found in mortuary contexts in Egypt and the Levant, and in Hittite temple assemblages in Anatolia. Neutron Activation Analysis (NAA) has enabled the source area of this special ceramic to be located in a geologically highly localised and geochemically distinctive area of western Cyprus. This discovery offers a new perspective on the spatial organisation of Cypriot economies in the production and exchange of elite goods around the eastern Mediterranean at this time.

Changes in resource use over time can provide insight into technological choice and the extent of long term stability in cultural practices. In this paper we re-evaluate the evidence for a marked demographic shift at the inception of the Early Iron Age at Troy by applying a robust macro scale analysis of changing ceramic resource use over the Late Bronze and Iron Age. We use a combination of new and legacy analytical datasets (NAA and XRF), from excavated ceramics, to evaluate the potential compositional range of local resources (based on comparisons with sediments from within a 10 km site radius). Results show a clear distinction between sediment-defined local and non-local ceramic compositional groups. Two discrete local ceramic resources have been previously identified and we confirm a third local resource for a major class of EIA handmade wares and cooking pots. This third source appears to derive from a residual resource on the Troy peninsula (rather than adjacent alluvial valleys). The presence of a group of large and heavy pithoi among the non-local groups raises questions about their regional or maritime origin.

Anthropogenically modified pigments are held to be some of the earliest, most unambiguous and persistent evidence for behavioural modernity, frequently (and often tenuously) invoked as material expression of symbolic thought and action. Recent finds, increases in the sophistication of analytic techniques and theoretical frameworks have renewed interest in ochre, reflected by a spike in actualistic studies, investigations of pigment morphology and geochemistry. Archaeological studies continue a bias towards Pleistocene pigments, while archaeometric research continues to focus on ochre from known source locations, and in Australia, ethnographically documented mines. Here I take a different tack, targeting Holocene ochres, focusing on pigments with at least one known, indisputably symbolic function- the production of rock art. As part of the physical and metaphorical (cultural) landscape, rock art offers a unique pigment archive as it remains in the location in which it was created. A decade since the first published application of portable X-ray Fluorescence (pXRF) to rock art there has been an absence of critical scrutiny and methodological development. Aiming to redress this, I use conventional and Synchrotron X-ray Diffraction, Micro Computed Tomography and Scanning Electron Microscopy to explain and evaluate pXRF. I develop novel methods of using geochemical data to identify paint mineralogy (including differentiating between paints of the same colour), recognise the chemical signatures of taphonomy and compare ochres from excavated contexts with rock art. Interpreting the resultant elemental profiles relies on understanding the complex taphonomy of pigments and the chemical expression of non-cultural phenomena, something not adequately addressed previously. This work therefore offers a non-invasive means by which large scale studies of archaeological pigments can be undertaken.

Archaeological use of non-destructive pXRF has been most systematically applied to the classification and provenancing of volcanic glass (obsidian) artefacts. Comparable work has yet to be developed for non-vitreous artefacts. We report results of pXRF analysis for a sample of grey to black (mafic) aboriginal hatchets from Sydney and adjacent coastal regions to the north and south. The study shows both broad and detailed classification is achievable depending on rock type and degree of elemental depletion or enrichment of the samples. PXRF analysis reveals not only distinct patterns of resource use between the three regions of this study but also enables a high degree of geographic resolution in the case of the basalt artefacts of our sample. We conclude that non-destructive pXRF is effective for reliable characterisation of non-vitreous stone artefacts that have a sufficiently complex and enriched compositional signature (i.e., unaltered basalts); with ~50% of the basalt hatchets in our sample matched with spatially and geologically specific sources.

PIXE-PIGME is a form of elemental analysis that uses a proton beam to irradiate powdered ceramic samples to isolate key trace elements (Grave et al. 1996). Owing to the availability of local testing facilities and expertise, this form of analysis was adopted to test selected samples from imported Giza Combed Ware jars held in the Boston Museum of Fine Arts and a reference sample of sherds from the Levant. Samples were obtained by taking a small 'clipping' from a larger sherd using a pair of ordinary pliers, or cut from a bigger piece using a small saw. These were then powdered by the in the N.G. McIntosh Centre for Quaternary Dating (University of Sydney), taking care to ensure that the slipped surface (where present) was not included in the powdered form for analysis. In the case of the Boston MFA samples, these were taken by the Museum's Conservation Department by drilling a hole either through the base or a clean section of the sherd. One again care was taken to ensure the drill obtained the sample from a clean surface and where necessary a small scraping of the surface was made. Sufficient powdered material of the Boston MFA jars remains to conduct further sampling in the future.

In the past decade there has been increasing interest in the archaeology of Spanish maritime exploration, colonization and trade in the western Pacific and Asia (Skowronek, 1998; 2009; Brunal-Perry et al., 2009; McKinnon and Raupp, 2011). Attention has been mostly on the north-west Pacific, associated with the operation of the highly successful Manila Galleon trade to the Philippines, where the treasures of the Americas were traded for the spices and goods of the Orient. In contrast, the several 16th- and early 17th-century Spanish expeditions to the southern Pacific searching for the 'Terra Australis' (Great Southern Land) and the gold-rich Ophir of King Solomon still remain relatively unknown (Spate, 1979; Camino, 2005).