Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/9128
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dc.contributor.authorFellows, Christopheren
dc.contributor.authorMurison, Robert Den
dc.contributor.authorRussell, Gregoryen
dc.date.accessioned2012-01-09T17:42:00Z-
dc.date.issued2011-
dc.identifier.citationMacromolecular Theory and Simulations, 20(6), p. 425-432en
dc.identifier.issn1521-3919en
dc.identifier.issn1022-1344en
dc.identifier.urihttps://hdl.handle.net/1959.11/9128-
dc.description.abstractAnalysis of published experimental data on monomeric radical diffusion in the emulsion polymerisation of styrene shows that it can be quantitatively described equally well by non-equilibrium diffusion from particles, where all parameters are derived from properties of the discrete phase, or by steady-state diffusion where all parameters are derived from properties of the continuous phase. The non-equilibrium model better describes an observed experimental trend to a reduced desorption rate coefficient at higher weight fraction of polymer in the particles. The theoretical upper bound of the non-equilibrium model is also higher than the theoretical upper bound of the steady-state model allowing fits to experimental data which must be discarded as anomalous in the continuous phase model.en
dc.languageenen
dc.publisherWiley-VCH Verlag GmbH & Co KGaAen
dc.relation.ispartofMacromolecular Theory and Simulationsen
dc.titleModel Discrimination of Radical Desorption Kinetics in Emulsion Polymerisationen
dc.typeJournal Articleen
dc.identifier.doi10.1002/mats.201100044en
dc.subject.keywordsApplied Statisticsen
dc.subject.keywordsPolymerisation Mechanismsen
local.contributor.firstnameChristopheren
local.contributor.firstnameRobert Den
local.contributor.firstnameGregoryen
local.subject.for2008010401 Applied Statisticsen
local.subject.for2008030305 Polymerisation Mechanismsen
local.subject.seo2008970103 Expanding Knowledge in the Chemical Sciencesen
local.profile.schoolSchool of Science and Technologyen
local.profile.schoolSchool of Science and Technologyen
local.profile.schoolChemistryen
local.profile.emailcfellows@une.edu.auen
local.profile.emailrmurison@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.identifier.epublicationsrecordune-20111130-16035en
local.publisher.placeGermanyen
local.format.startpage425en
local.format.endpage432en
local.identifier.scopusid79960251879en
local.peerreviewedYesen
local.identifier.volume20en
local.identifier.issue6en
local.contributor.lastnameFellowsen
local.contributor.lastnameMurisonen
local.contributor.lastnameRussellen
dc.identifier.staffune-id:cfellowsen
dc.identifier.staffune-id:rmurisonen
local.profile.orcid0000-0002-8976-8651en
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.identifier.unepublicationidune:9318en
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
local.title.maintitleModel Discrimination of Radical Desorption Kinetics in Emulsion Polymerisationen
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.search.authorFellows, Christopheren
local.search.authorMurison, Robert Den
local.search.authorRussell, Gregoryen
local.uneassociationUnknownen
local.identifier.wosid000293267100005en
local.year.published2011en
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