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Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/7537
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dc.contributor.authorTrotter, KDen
dc.contributor.authorTaylor, Michelle Keilyen
dc.contributor.authorForgie, JCen
dc.contributor.authorReglinski, Jen
dc.contributor.authorBerlouis, LEAen
dc.contributor.authorKennedy, ARen
dc.contributor.authorSpickett, CMen
dc.contributor.authorSowden, RJen
dc.date.accessioned2011-05-25T10:01:00Z-
dc.date.issued2010-
dc.identifier.citationInorganica Chimica Acta, 363(7), p. 1529-1538en
dc.identifier.issn1873-3255en
dc.identifier.issn0020-1693en
dc.identifier.urihttps://hdl.handle.net/1959.11/7537-
dc.description.abstractA series of cis and trans tetradentate copper macrocyclic complexes, of ring size 14–16, that employ amine and thioether donor groups are reported. Apart from 5,6,15,16-bisbenzo-8,13-diaza-1,4-dithia-cyclohexadecane copper(I) (cis-[Cu(H4NbuSen)]+) all of the complexes are obtained in the copper(II) form. Crystallographic analysis shows that the copper(II) complexes all adopt a distorted planar geometry around the copper. In contrast, cis-[Cu(H4NbuSen)]+ is found to adopt a distorted tetrahedral geometry. The complexes were subjected to electrochemical analysis in water and acetonitrile. The effect of the solvent, positions of the donor atoms (cis/trans) on E1/2 is discussed as is the comparison of the electrochemical behaviour of these complexes with their parent Schiff base macrocycles.en
dc.languageenen
dc.publisherElsevier BVen
dc.relation.ispartofInorganica Chimica Actaen
dc.titleThe structural and electrochemical consequences of hydrogenating copper N₂S₂ Schiff base macrocyclesen
dc.typeJournal Articleen
dc.identifier.doi10.1016/j.ica.2010.01.012en
dc.subject.keywordsTransition Metal Chemistryen
local.contributor.firstnameKDen
local.contributor.firstnameMichelle Keilyen
local.contributor.firstnameJCen
local.contributor.firstnameJen
local.contributor.firstnameLEAen
local.contributor.firstnameARen
local.contributor.firstnameCMen
local.contributor.firstnameRJen
local.subject.for2008030207 Transition Metal Chemistryen
local.subject.seo2008970103 Expanding Knowledge in the Chemical Sciencesen
local.profile.schoolSchool of Science and Technologyen
local.profile.emailmtaylo53@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.identifier.epublicationsrecordune-20110323-172357en
local.publisher.placeNetherlandsen
local.format.startpage1529en
local.format.endpage1538en
local.identifier.scopusid77950296069en
local.peerreviewedYesen
local.identifier.volume363en
local.identifier.issue7en
local.contributor.lastnameTrotteren
local.contributor.lastnameTayloren
local.contributor.lastnameForgieen
local.contributor.lastnameReglinskien
local.contributor.lastnameBerlouisen
local.contributor.lastnameKennedyen
local.contributor.lastnameSpicketten
local.contributor.lastnameSowdenen
dc.identifier.staffune-id:mtaylo53en
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.identifier.unepublicationidune:7705en
dc.identifier.academiclevelAcademicen
local.title.maintitleThe structural and electrochemical consequences of hydrogenating copper N₂S₂ Schiff base macrocyclesen
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.search.authorTrotter, KDen
local.search.authorTaylor, Michelle Keilyen
local.search.authorForgie, JCen
local.search.authorReglinski, Jen
local.search.authorBerlouis, LEAen
local.search.authorKennedy, ARen
local.search.authorSpickett, CMen
local.search.authorSowden, RJen
local.uneassociationUnknownen
local.year.published2010en
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