Please use this identifier to cite or link to this item:
https://hdl.handle.net/1959.11/59120
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Puschnig, Johannes | en |
dc.contributor.author | Jevric, Martyn | en |
dc.contributor.author | Sumby, Christopher J | en |
dc.contributor.author | Greatrex, Ben W | en |
dc.date.accessioned | 2024-05-08T23:06:19Z | - |
dc.date.available | 2024-05-08T23:06:19Z | - |
dc.date.issued | 2024-01-19 | - |
dc.identifier.citation | The Journal of Organic Chemistry, 89(2), p. 1315-1319 | en |
dc.identifier.issn | 1520-6904 | en |
dc.identifier.issn | 0022-3263 | en |
dc.identifier.uri | https://hdl.handle.net/1959.11/59120 | - |
dc.description.abstract | <p>The intramolecular enamine-Mizoroki–Heck reaction allows for the construction of nitrogen-containing heterocycles, although the related intermolecular version is less known. The reactions of enamines derived from Cyrene were investigated under Mizoroki–Heck conditions. An optimization study was used to identify that 1.5 mol % Pd(dba)<sub>2</sub> with PCy<sub>3</sub> in xylene at reflux temperature gave the highest yield with electron-rich aryl iodides. Arylation occurred predominantly at the C–N center of the enamine, while the diastereoselectivity was dependent on the nitrogen substitution in the enamine.</p> | en |
dc.language | en | en |
dc.publisher | American Chemical Society | en |
dc.relation.ispartof | The Journal of Organic Chemistry | en |
dc.title | Intermolecular Enamine Mizoroki–Heck Reactions on a Bio-Derived Scaffold | en |
dc.type | Journal Article | en |
dc.identifier.doi | 10.1021/acs.joc.3c02415 | en |
local.contributor.firstname | Johannes | en |
local.contributor.firstname | Martyn | en |
local.contributor.firstname | Christopher J | en |
local.contributor.firstname | Ben W | en |
local.relation.isfundedby | ARC | en |
local.profile.school | School of Rural Medicine | en |
local.profile.school | School of Rural Medicine | en |
local.profile.email | mjevric@une.edu.au | en |
local.profile.email | bgreatre@une.edu.au | en |
local.output.category | C1 | en |
local.grant.number | E210100163 | en |
local.record.place | au | en |
local.record.institution | University of New England | en |
local.publisher.place | United States of America | en |
local.format.startpage | 1315 | en |
local.format.endpage | 1319 | en |
local.peerreviewed | Yes | en |
local.identifier.volume | 89 | en |
local.identifier.issue | 2 | en |
local.contributor.lastname | Puschnig | en |
local.contributor.lastname | Jevric | en |
local.contributor.lastname | Sumby | en |
local.contributor.lastname | Greatrex | en |
dc.identifier.staff | une-id:mjevric | en |
dc.identifier.staff | une-id:bgreatre | en |
local.profile.orcid | 0000-0002-0356-4966 | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.identifier.unepublicationid | une:1959.11/59120 | en |
dc.identifier.academiclevel | Academic | en |
dc.identifier.academiclevel | Academic | en |
dc.identifier.academiclevel | Academic | en |
dc.identifier.academiclevel | Academic | en |
local.title.maintitle | Intermolecular Enamine Mizoroki–Heck Reactions on a Bio-Derived Scaffold | en |
local.relation.fundingsourcenote | The Australian Government with a Research Training Program (RTP) Scholarship | en |
local.output.categorydescription | C1 Refereed Article in a Scholarly Journal | en |
local.relation.grantdescription | ARC/E210100163 | en |
local.search.author | Puschnig, Johannes | en |
local.search.author | Jevric, Martyn | en |
local.search.author | Sumby, Christopher J | en |
local.search.author | Greatrex, Ben W | en |
local.uneassociation | Yes | en |
local.atsiresearch | No | en |
local.sensitive.cultural | No | en |
local.year.published | 2024 | en |
local.fileurl.closedpublished | https://rune.une.edu.au/web/retrieve/daf05824-d75d-423c-9cf8-346bba61163b | en |
local.subject.for2020 | 3405 Organic chemistry | en |
local.subject.seo2020 | tbd | en |
local.profile.affiliationtype | UNE Affiliation | en |
local.profile.affiliationtype | External Affiliation | en |
local.profile.affiliationtype | External Affiliation | en |
local.profile.affiliationtype | UNE Affiliation | en |
local.date.moved | 2024-05-09 | en |
Appears in Collections: | Journal Article |
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