Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/20114
Title: Sulfide metasomatism and the mobility of gold in the lithospheric mantle
Contributor(s): Saunders, James  (author)orcid ; Pearson, N J (author); O'Reilly, Suzanne Y (author); Griffin, W L (author)
Publication Date: 2015
DOI: 10.1016/j.chemgeo.2015.06.016
Handle Link: https://hdl.handle.net/1959.11/20114
Abstract: Gold is a strongly chalcophile element and its concentration and behaviour in the mantle are intimately connected to the nature, abundance and mobility of sulfide phases. In this study Au has been analysed together with a suite of chalcophile and siderophile elements in sulfides hosted in 31 mantle-derived xenoliths from Spitsbergen in the Svalbard Archipelago. These data have been combined with analysis of silicate phases to assess the mobility of Au, and sulfides in general, during mantle processes. The 31 samples comprise lherzolites, harzburgites, dunites and a wehrlite. Several lherzolites contain amphibole and apatite, and two are cross-cut by amphibole veins. The REE patterns in clinopyroxene reveal three geochemically distinct groups of peridotites. Group I samples have flat or LREE depleted patterns ((La/Yb)n<1); Group II samples show sinuous REE patterns; and Group III samples showLREE enrichmentwith moderately steep slopes ((La/Yb)n>1). The sulfides hosted in the Group I samples have very heterogeneous Au compositions (1.9 ± 1.4 ppm), whereas those hosted in Groups II and III samples have lower and more homogenous Au concentrations (Group II Au: 0.66 ± 0.60 ppm; Group III Au: 0.53 ± 0.57 ppm). A chromatographic metasomatic model is proposed to explain the variations between the three groups of samples. The LREE enrichment, and common inclusion of amphibole in the Group III samples is consistent with modification by a carbonate-rich melt. It is interpreted that these samples were located close to the metasomatic conduit. The sulfide homogeneity in these samples results from extensive equilibration with the metasomatic agent; Au has partitioned into the fluid phase, reducing the Au content of these sulfides. The Group I samples show little to no metasomatic alteration in the silicate phases, indicating they were located far from the conduit. The agents that have affected these samples have been modified by extensive fractionation and wall-rock interaction during percolation through the mantle, becoming enriched in Au. Group II samples are inferred to have been located at an intermediate distance from the conduit with silicate and sulfide characteristics that fall in between those from the other two groups.
Publication Type: Journal Article
Source of Publication: Chemical Geology, v.410, p. 149-161
Publisher: Elsevier BV
Place of Publication: Netherlands
ISSN: 1872-6836
0009-2541
Fields of Research (FoR) 2008: 040304 Igneous and Metamorphic Petrology
Fields of Research (FoR) 2020: 370503 Igneous and metamorphic petrology
Socio-Economic Objective (SEO) 2008: 970104 Expanding Knowledge in the Earth Sciences
Socio-Economic Objective (SEO) 2020: 280107 Expanding knowledge in the earth sciences
Peer Reviewed: Yes
HERDC Category Description: C1 Refereed Article in a Scholarly Journal
Appears in Collections:Journal Article

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