Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/20008
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dc.contributor.authorAdam, Madeleine Ken
dc.contributor.authorHu, Yingxueen
dc.contributor.authorPoisson, Jessica Sen
dc.contributor.authorPottage, Matthew Jen
dc.contributor.authorBen, Robert Nen
dc.contributor.authorWilkinson, Brendanen
dc.date.accessioned2017-02-16T15:17:00Z
dc.date.issued2017en
dc.identifier.citationCarbohydrate Research, v.439, p. 1-8en
dc.identifier.issn0008-6215en
dc.identifier.issn1873-426Xen
dc.identifier.urihttps://hdl.handle.net/1959.11/20008en
dc.description.abstractCryopreservation is an important technique employed for the storage and preservation of biological tissues and cells. The limited effectiveness and significant toxicity of conventionally-used cryoprotectants, such as DMSO, have prompted efforts toward the rational design of less toxic alternatives, including carbohydrate-based surfactants. In this paper, we report the modular synthesis and ice recrystallization inhibition (IRI) activity of a library of variably substituted, carbohydrate-based fluorosurfactants. Carbohydrate-based fluorosurfactants possessed a variable mono- or disaccharide head group appended to a hydrophobic fluoroalkyl-substituted azobenzene tail group. Light-addressable fluorosurfactants displayed weak-to-moderate IRI activity that could be tuned through selection of carbohydrate head group, position of the trifluoroalkyl group on the azobenzene ring, and isomeric state of the azobenzene tail fragment.en
dc.languageenen
dc.publisherPergamon Pressen
dc.relation.ispartofCarbohydrate Researchen
dc.titlePhotoswitchable carbohydrate-based fluorosurfactants as tuneable ice recrystallization inhibitorsen
dc.typeJournal Articleen
dc.identifier.doi10.1016/j.carres.2016.12.004en
dc.subject.keywordsBiologically Active Moleculesen
dc.subject.keywordsSynthesis of Materialsen
dc.subject.keywordsOrganic Chemical Synthesisen
local.contributor.firstnameMadeleine Ken
local.contributor.firstnameYingxueen
local.contributor.firstnameJessica Sen
local.contributor.firstnameMatthew Jen
local.contributor.firstnameRobert Nen
local.contributor.firstnameBrendanen
local.subject.for2008030401 Biologically Active Moleculesen
local.subject.for2008030306 Synthesis of Materialsen
local.subject.for2008030503 Organic Chemical Synthesisen
local.subject.seo2008970106 Expanding Knowledge in the Biological Sciencesen
local.subject.seo2008929999 Health not elsewhere classifieden
local.subject.seo2008970103 Expanding Knowledge in the Chemical Sciencesen
local.profile.schoolSchool of Science and Technologyen
local.profile.emailbwilkin7@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.identifier.epublicationsrecordune-chute-20170114-213113en
local.publisher.placeUnited Kingdomen
local.format.startpage1en
local.format.endpage8en
local.peerreviewedYesen
local.identifier.volume439en
local.contributor.lastnameAdamen
local.contributor.lastnameHuen
local.contributor.lastnamePoissonen
local.contributor.lastnamePottageen
local.contributor.lastnameBenen
local.contributor.lastnameWilkinsonen
dc.identifier.staffune-id:bwilkin7en
local.profile.orcid0000-0003-1866-6540en
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.identifier.unepublicationidune:20206en
dc.identifier.academiclevelAcademicen
local.title.maintitlePhotoswitchable carbohydrate-based fluorosurfactants as tuneable ice recrystallization inhibitorsen
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.relation.grantdescriptionARC/DE130101673en
local.description.statisticsepubsVisitors: 44<br />Views: 214<br />Downloads: 0en
local.search.authorAdam, Madeleine Ken
local.search.authorHu, Yingxueen
local.search.authorPoisson, Jessica Sen
local.search.authorPottage, Matthew Jen
local.search.authorBen, Robert Nen
local.search.authorWilkinson, Brendanen
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