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Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/15495
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dc.contributor.authorAbernethy, Colin Den
dc.contributor.authorCodd, Gareth Men
dc.contributor.authorSpicer, Mark Den
dc.contributor.authorTaylor, Michelle Ken
dc.date.accessioned2014-08-20T14:03:00Z-
dc.date.issued2003-
dc.identifier.citationJournal of the American Chemical Society, 125(5), p. 1128-1129en
dc.identifier.issn1520-5126en
dc.identifier.issn0002-7863en
dc.identifier.issn1943-2984en
dc.identifier.urihttps://hdl.handle.net/1959.11/15495-
dc.description.abstractReaction of 1,3-dimesitylimidazol-2-ylidene and trichloro-oxo-vanadium(V) yields an air stable 1:1 adduct, which demonstrates the utility of N-heterocyclic carbenes to stabilize metal complexes in high oxidation states. The molecular structure of this compound reveals that the chloride ligands cis to the carbene are oriented toward the C'carbene' atom. Density functional theory calculations show that a bonding interaction occurs between lone pairs of these chlorides and the formally unoccupied p-orbital of the carbene. Previous studies indicated that this orbital was not involved in the bonding of N-heterocyclic carbenes to transition metals. The observed interaction therefore represents a new bonding mode for these widely used ligands.en
dc.languageenen
dc.publisherAmerican Chemical Societyen
dc.relation.ispartofJournal of the American Chemical Societyen
dc.titleA Highly Stable N-Heterocyclic Carbene Complex of Trichloro-oxo-vanadium(V) Displaying Novel Cl-Ccarbene Bonding Interactionsen
dc.typeJournal Articleen
dc.identifier.doi10.1021/ja0276321en
dc.subject.keywordsStructural Chemistry and Spectroscopyen
dc.subject.keywordsTransition Metal Chemistryen
dc.subject.keywordsElectrochemistryen
local.contributor.firstnameColin Den
local.contributor.firstnameGareth Men
local.contributor.firstnameMark Den
local.contributor.firstnameMichelle Ken
local.subject.for2008030606 Structural Chemistry and Spectroscopyen
local.subject.for2008030207 Transition Metal Chemistryen
local.subject.for2008030604 Electrochemistryen
local.subject.seo2008970103 Expanding Knowledge in the Chemical Sciencesen
local.profile.schoolSchool of Science and Technologyen
local.profile.emailmtaylo53@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.identifier.epublicationsrecordune-20140818-162734en
local.publisher.placeUnited States of Americaen
local.format.startpage1128en
local.format.endpage1129en
local.identifier.scopusid0037419890en
local.peerreviewedYesen
local.identifier.volume125en
local.identifier.issue5en
local.contributor.lastnameAbernethyen
local.contributor.lastnameCodden
local.contributor.lastnameSpiceren
local.contributor.lastnameTayloren
dc.identifier.staffune-id:mtaylo53en
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.identifier.unepublicationidune:15719en
local.identifier.handlehttps://hdl.handle.net/1959.11/15495en
dc.identifier.academiclevelAcademicen
local.title.maintitleA Highly Stable N-Heterocyclic Carbene Complex of Trichloro-oxo-vanadium(V) Displaying Novel Cl-Ccarbene Bonding Interactionsen
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.search.authorAbernethy, Colin Den
local.search.authorCodd, Gareth Men
local.search.authorSpicer, Mark Den
local.search.authorTaylor, Michelle Ken
local.uneassociationUnknownen
local.year.published2003en
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