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Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/15473
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dc.contributor.authorAl-Hamzah, Alien
dc.contributor.authorWallace, Andrewen
dc.contributor.authorEast, Christopher Pen
dc.contributor.authorDoherty, William O Sen
dc.contributor.authorSmith, Ericaen
dc.contributor.authorFellows, Christopheren
dc.date.accessioned2014-08-13T11:21:00Z-
dc.date.issued2014-
dc.identifier.citationIndustrial & Engineering Chemistry Research, 53(21), p. 8793-8803en
dc.identifier.issn1520-5045en
dc.identifier.issn0888-5885en
dc.identifier.urihttps://hdl.handle.net/1959.11/15473-
dc.description.abstractAn intrinsic exposed core optical fiber sensor (IECOFS) made from fused silica was used to monitor the crystallization of calcium carbonate (CaCO₃) and CaCO₃/calcium sulfate (CaSO₄) composite at 100 and 120 °C in the absence and presence of low-molar-mass (Mn ≤ 2000) poly(acrylic acid) (PAA) with different end groups. The IECOFS responded only to deposition and growth processes on the fiber surface rather than changes occurring in the bulk of the solution. Hexyl isobutyrate-terminated PAA (Mn = 1400) and hexadecyl isobutyrate-terminated PAA (Mn = 1700) were the most effective species in preventing CaCO₃ deposition. Phase transformation from vaterite to aragonite/calcite decreased with increasing hydrophobicity of the PAA end group. Low-molar-mass PAA at 10 ppm showed very significant inhibition of CaCO₃/CaSO₄ composite formation for all end groups investigated.en
dc.languageenen
dc.publisherAmerican Chemical Societyen
dc.relation.ispartofIndustrial & Engineering Chemistry Researchen
dc.titleInhibition by Poly(acrylic acid) and Morphological Changes in Calcium Carbonate and Calcium Carbonate/Calcium Sulfate Crystallization on Silica Fibersen
dc.typeJournal Articleen
dc.identifier.doi10.1021/ie500911gen
dc.subject.keywordsTheory and Design of Materialsen
dc.subject.keywordsChemical Characterisation of Materialsen
dc.subject.keywordsPhysical Chemistry of Materialsen
local.contributor.firstnameAlien
local.contributor.firstnameAndrewen
local.contributor.firstnameChristopher Pen
local.contributor.firstnameWilliam O Sen
local.contributor.firstnameEricaen
local.contributor.firstnameChristopheren
local.subject.for2008030307 Theory and Design of Materialsen
local.subject.for2008030304 Physical Chemistry of Materialsen
local.subject.for2008030301 Chemical Characterisation of Materialsen
local.subject.seo2008970103 Expanding Knowledge in the Chemical Sciencesen
local.subject.seo2008861501 Industrial Instrumentsen
local.subject.seo2008860602 Inorganic Industrial Chemicalsen
local.profile.schoolSchool of Science and Technologyen
local.profile.schoolSchool of Science and Technologyen
local.profile.schoolSchool of Science and Technologyen
local.profile.emailawallac7@une.edu.auen
local.profile.emailceast3@une.edu.auen
local.profile.emailesmith32@une.edu.auen
local.profile.emailcfellows@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.identifier.epublicationsrecordune-20140812-083234en
local.publisher.placeUnited States of Americaen
local.format.startpage8793en
local.format.endpage8803en
local.identifier.scopusid84901701332en
local.peerreviewedYesen
local.identifier.volume53en
local.identifier.issue21en
local.contributor.lastnameAl-Hamzahen
local.contributor.lastnameWallaceen
local.contributor.lastnameEasten
local.contributor.lastnameDohertyen
local.contributor.lastnameSmithen
local.contributor.lastnameFellowsen
dc.identifier.staffune-id:awallac7en
dc.identifier.staffune-id:ceast3en
dc.identifier.staffune-id:esmith32en
dc.identifier.staffune-id:cfellowsen
local.profile.orcid0000-0002-8090-4768en
local.profile.orcid0000-0002-8976-8651en
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.identifier.unepublicationidune:15690en
local.identifier.handlehttps://hdl.handle.net/1959.11/15473en
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
local.title.maintitleInhibition by Poly(acrylic acid) and Morphological Changes in Calcium Carbonate and Calcium Carbonate/Calcium Sulfate Crystallization on Silica Fibersen
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.search.authorAl-Hamzah, Alien
local.search.authorWallace, Andrewen
local.search.authorEast, Christopher Pen
local.search.authorDoherty, William O Sen
local.search.authorSmith, Ericaen
local.search.authorFellows, Christopheren
local.uneassociationUnknownen
local.identifier.wosid000336635200015en
local.year.published2014en
local.subject.for2020340307 Structure and dynamics of materialsen
local.subject.for2020340302 Macromolecular materialsen
local.subject.for2020340301 Inorganic materials (incl. nanomaterials)en
local.subject.seo2020280105 Expanding knowledge in the chemical sciencesen
local.subject.seo2020241001 Industrial instrumentsen
local.subject.seo2020240906 Inorganic industrial chemicalsen
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