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Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/14909
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dc.contributor.authorOliver, James Den
dc.contributor.authorRosser, Adam Aen
dc.contributor.authorFellows, Chrisen
dc.contributor.authorGuillaneuf, Yohannen
dc.contributor.authorClement, Jean-Louisen
dc.contributor.authorGaborieau, Marionen
dc.contributor.authorCastignolles, Patriceen
dc.date.accessioned2014-04-30T13:22:00Z-
dc.date.issued2014-
dc.identifier.citationAnalytica Chimica Acta, v.809, p. 183-193en
dc.identifier.issn1873-4324en
dc.identifier.issn0003-2670en
dc.identifier.urihttps://hdl.handle.net/1959.11/14909-
dc.description.abstractDirect UV detection of carbohydrates in free solution capillary electrophoresis at 270 nm is made possible by a photo-oxidation reaction. Glucose, rhamnose and xylose were shown to have unique UV absorption spectra hypothesizing different UV absorbing intermediates for their respective photo-oxidation. NMR spectroscopy of the photo-oxidation end products proved they consisted of carboxylates and not malondialdehyde as previously theorized and that oxygen thus plays a key role in the photo-oxidation pathway. Adding the photo-initiator Irgacure® 2959 in the background electrolyte increased sensitivity by 40% at an optimum concentration of 1 x 10⁻⁴mM and 1 x 10⁻⁸mM for conventional 50 μm i.d. capillaries and for the corresponding extended light path capillaries, respectively.en
dc.languageenen
dc.publisherElsevier BVen
dc.relation.ispartofAnalytica Chimica Actaen
dc.titleUnderstanding and improving direct UV detection of monosaccharides and disaccharides in free solution capillary electrophoresisen
dc.typeJournal Articleen
dc.identifier.doi10.1016/j.aca.2013.12.001en
dc.subject.keywordsSeparation Scienceen
local.contributor.firstnameJames Den
local.contributor.firstnameAdam Aen
local.contributor.firstnameChrisen
local.contributor.firstnameYohannen
local.contributor.firstnameJean-Louisen
local.contributor.firstnameMarionen
local.contributor.firstnamePatriceen
local.subject.for2008030108 Separation Scienceen
local.subject.seo2008829899 Environmentally Sustainable Plant Production not elsewhere classifieden
local.subject.seo2008820399 Industrial Crops not elsewhere classifieden
local.subject.seo2008850501 Biofuel (Biomass) Energyen
local.profile.schoolChemistryen
local.profile.schoolSchool of Science and Technologyen
local.profile.schoolSchool of Science and Technologyen
local.profile.schoolChemistryen
local.profile.schoolIT Voice Systemsen
local.profile.schoolChemistryen
local.profile.schoolChemistryen
local.profile.emailarosser3@une.edu.auen
local.profile.emailcfellows@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.identifier.epublicationsrecordune-20140221-104759en
local.publisher.placeNetherlandsen
local.format.startpage183en
local.format.endpage193en
local.identifier.scopusid84891933230en
local.peerreviewedYesen
local.identifier.volume809en
local.contributor.lastnameOliveren
local.contributor.lastnameRosseren
local.contributor.lastnameFellowsen
local.contributor.lastnameGuillaneufen
local.contributor.lastnameClementen
local.contributor.lastnameGaborieauen
local.contributor.lastnameCastignollesen
dc.identifier.staffune-id:arosser3en
dc.identifier.staffune-id:cfellowsen
local.profile.orcid0000-0002-4123-7704en
local.profile.orcid0000-0002-8976-8651en
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.identifier.unepublicationidune:15124en
local.identifier.handlehttps://hdl.handle.net/1959.11/14909en
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
local.title.maintitleUnderstanding and improving direct UV detection of monosaccharides and disaccharides in free solution capillary electrophoresisen
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.search.authorOliver, James Den
local.search.authorRosser, Adam Aen
local.search.authorFellows, Chrisen
local.search.authorGuillaneuf, Yohannen
local.search.authorClement, Jean-Louisen
local.search.authorGaborieau, Marionen
local.search.authorCastignolles, Patriceen
local.uneassociationUnknownen
local.identifier.wosid000329580500024en
local.year.published2014en
local.subject.for2020340109 Separation scienceen
local.subject.seo2020170801 Biofuel energyen
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