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Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/13064
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dc.contributor.authorGuerrro-Sanchez, Carlosen
dc.contributor.authorHarrisson, Simonen
dc.contributor.authorKeddie, Danielen
dc.date.accessioned2013-07-22T14:20:00Z-
dc.date.issued2013-
dc.identifier.citationMacromolecular Symposia, 325-326(1), p. 38-46en
dc.identifier.issn1521-3900en
dc.identifier.issn1022-1360en
dc.identifier.urihttps://hdl.handle.net/1959.11/13064-
dc.description.abstractA new high-throughput experimental technique, namely automated parallel freeze-evacuate-thaw degassing method, is applied for the facile, rapid and reliable determination of reactivity ratios in copolymerization systems. The approach allowed carrying out a detailed kinetic investigation of the reversible addition-fragmentation chain transfer (RAFT) copolymerization of methyl acrylate (MA) with vinyl acetate (VAC) monomers in 2-methyl-2-butanol at 60℃. Thereafter, the reactivity ratios of this copolymerization system were estimated utilizing the obtained kinetic data and a computer program based on the visualization of the sum of residual space method. The obtained reactivity ratios of the system (rma = 8.2 and rvac = 0.17) are comparable to values previously reported in the literature, which demonstrates the utility of this approach.en
dc.languageenen
dc.publisherWiley-VCH Verlag GmbH & Co KGaAen
dc.relation.ispartofMacromolecular Symposiaen
dc.titleHigh-Throughput Method for RAFT Kinetic Investigations and Estimation of Reactivity Ratios in Copolymerization Systemsen
dc.typeJournal Articleen
dc.identifier.doi10.1002/masy.201200038en
dc.subject.keywordsFree Radical Chemistryen
dc.subject.keywordsSynthesis of Materialsen
dc.subject.keywordsPolymerisation Mechanismsen
local.contributor.firstnameCarlosen
local.contributor.firstnameSimonen
local.contributor.firstnameDanielen
local.subject.for2008030305 Polymerisation Mechanismsen
local.subject.for2008030501 Free Radical Chemistryen
local.subject.for2008030306 Synthesis of Materialsen
local.subject.seo2008970103 Expanding Knowledge in the Chemical Sciencesen
local.profile.schoolChemistryen
local.profile.schoolChemistryen
local.profile.schoolSchool of Science and Technologyen
local.profile.emaildkeddie@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.identifier.epublicationsrecordune-20130513-111447en
local.publisher.placeGermanyen
local.format.startpage38en
local.format.endpage46en
local.peerreviewedYesen
local.identifier.volume325-326en
local.identifier.issue1en
local.contributor.lastnameGuerrro-Sanchezen
local.contributor.lastnameHarrissonen
local.contributor.lastnameKeddieen
dc.identifier.staffune-id:dkeddieen
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.identifier.unepublicationidune:13275en
dc.identifier.academiclevelAcademicen
local.title.maintitleHigh-Throughput Method for RAFT Kinetic Investigations and Estimation of Reactivity Ratios in Copolymerization Systemsen
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.search.authorGuerrro-Sanchez, Carlosen
local.search.authorHarrisson, Simonen
local.search.authorKeddie, Danielen
local.uneassociationUnknownen
local.year.published2013en
local.subject.for2020340306 Polymerisation mechanismsen
local.subject.for2020340501 Free radical chemistryen
local.subject.for2020340207 Metal organic frameworksen
local.subject.seo2020280105 Expanding knowledge in the chemical sciencesen
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