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Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/12616
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dc.contributor.authorMiron, David Jen
dc.contributor.authorKendell, Shaneen
dc.contributor.authorMunshi, Alaa Men
dc.contributor.authorAlanazi, Abdullah Ken
dc.contributor.authorBrown, Trevor Cen
dc.date.accessioned2013-05-23T11:28:00Z-
dc.date.issued2013-
dc.identifier.citationInternational Journal of Chemical Kinetics, 45(6), p. 374-386en
dc.identifier.issn1097-4601en
dc.identifier.issn0538-8066en
dc.identifier.urihttps://hdl.handle.net/1959.11/12616-
dc.description.abstractTime-varying linear regression via flexible least squares is used to determine temperature-dependent kinetic parameters during low-pressure, steady-state, temperature-programmed desorption from catalytic surfaces. The flexible least squares approach optimizes time-varying parameters by minimizing dynamic and measurement discrepancies between a linear theoretical model and experimental data using linear regression. The effectiveness of this approach is demonstrated by calculation of accurate temperature-dependent activation energies, preexponential factors, and differential conversion functions for the evolution of 3-methyl-2-oxetanone (β-lactone) during the selective oxidation of isobutane over aluminum phosphomolybdates.en
dc.languageenen
dc.publisherJohn Wiley & Sons, Incen
dc.relation.ispartofInternational Journal of Chemical Kineticsen
dc.titleTime-Varying Flexible Least Squares for Thermal Desorption of Gasesen
dc.typeJournal Articleen
dc.identifier.doi10.1002/kin.20772en
dc.subject.keywordsReaction Kinetics and Dynamicsen
dc.subject.keywordsCatalysis and Mechanisms of Reactionsen
dc.subject.keywordsPhysical Chemistry of Materialsen
local.contributor.firstnameDavid Jen
local.contributor.firstnameShaneen
local.contributor.firstnameAlaa Men
local.contributor.firstnameAbdullah Ken
local.contributor.firstnameTrevor Cen
local.subject.for2008030703 Reaction Kinetics and Dynamicsen
local.subject.for2008030304 Physical Chemistry of Materialsen
local.subject.for2008030601 Catalysis and Mechanisms of Reactionsen
local.subject.seo2008970109 Expanding Knowledge in Engineeringen
local.subject.seo2008970103 Expanding Knowledge in the Chemical Sciencesen
local.profile.schoolAdministrationen
local.profile.schoolComputer Scienceen
local.profile.schoolComputer Scienceen
local.profile.schoolIT Voice Systemsen
local.profile.schoolSchool of Science and Technologyen
local.profile.emaildmiron@une.edu.auen
local.profile.emailaalanaz4@une.edu.auen
local.profile.emailtbrown3@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.identifier.epublicationsrecordune-20130507-080531en
local.publisher.placeUnited States of Americaen
local.format.startpage374en
local.format.endpage386en
local.identifier.scopusid84876722716en
local.peerreviewedYesen
local.identifier.volume45en
local.identifier.issue6en
local.contributor.lastnameMironen
local.contributor.lastnameKendellen
local.contributor.lastnameMunshien
local.contributor.lastnameAlanazien
local.contributor.lastnameBrownen
dc.identifier.staffune-id:dmironen
dc.identifier.staffune-id:skendellen
dc.identifier.staffune-id:amunshien
dc.identifier.staffune-id:aalanaz4en
dc.identifier.staffune-id:tbrown3en
local.profile.orcid0000-0003-2157-5439en
local.profile.orcid0000-0003-0008-1309en
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.identifier.unepublicationidune:12823en
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
dc.identifier.academiclevelAcademicen
local.title.maintitleTime-Varying Flexible Least Squares for Thermal Desorption of Gasesen
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.search.authorMiron, David Jen
local.search.authorKendell, Shaneen
local.search.authorMunshi, Alaa Men
local.search.authorAlanazi, Abdullah Ken
local.search.authorBrown, Trevor Cen
local.uneassociationUnknownen
local.identifier.wosid000318176700004en
local.year.published2013en
local.subject.for2020340607 Reaction kinetics and dynamicsen
local.subject.for2020340302 Macromolecular materialsen
local.subject.for2020340601 Catalysis and mechanisms of reactionsen
local.subject.seo2020280110 Expanding knowledge in engineeringen
local.subject.seo2020280105 Expanding knowledge in the chemical sciencesen
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