Eu speciation in apatite at 1 bar: An experimental study of valence-state partitioning by XANES, lattice strain, and Eu/Eu* in basaltic systems

Author(s)
Tailby, Nicholas D
Trail, Dustin
Watson, Bruce
Lanzirotti, Antonio
Newville, Matthew
Wang, Yanling
Publication Date
2023-05-01
Abstract
<p>Partition coefficients for rare earth elements (REEs) between apatite and basaltic melt were determined as a function of oxygen fugacity (<i>f<sub>O2</sub></i>; iron-wüstite to hematite-magnetite buffers) at 1 bar and between 1110 and 1175 °C. Apatite-melt partitioning data for R<sup>EE3+</sup> (La, Sm, Gd, Lu) show near constant values at all experimental conditions, while bulk Eu becomes more incompatible (with an increasing negative anomaly) with decreasing <i>f<sub>O2</sub></i>. Experiments define three apatite calibrations that can theoretically be used as redox sensors. </p>
Citation
The American Mineralogist, 108(5), p. 789-813
ISSN
1945-3027
0003-004X
Link
Publisher
Mineralogical Society of America
Title
Eu speciation in apatite at 1 bar: An experimental study of valence-state partitioning by XANES, lattice strain, and Eu/Eu* in basaltic systems
Type of document
Journal Article
Entity Type
Publication

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