| Author(s) |
Thenarukandiyil, Ranjeesh
Paenurk, Eno
Wong, Anthony
Fridman, Natalia
Karton, Amir
Carmieli, Raanan
Ménard, Gabriel
Gershoni-Poranne, Renana
de Ruiter, Graham
|
| Publication Date |
2021-12-06
|
| Abstract |
<p>Metal-ligand cooperation is an important aspect in earth-abundant metal catalysis. Utilizing ligands as electron reservoirs to supplement the redox chemistry of the metal has resulted in many new exciting discoveries. Here, we demonstrate that iron bipyridine-diimine (BDI) complexes exhibit an extensive electron-transfer series that spans a total of five oxidation states, ranging from the trication [Fe(BDI)]<sup>3+</sup> to the monoanion [Fe(BDI]<sup>-1</sup>. Structural characterization by X-ray crystallography revealed the multifaceted redox noninnocence of the BDI ligand, while spectroscopic (e.g., <sup>57</sup>Fe Mössbauer and EPR spectroscopy) and computational studies were employed to elucidate the electronic structure of the isolated complexes, which are further discussed in this report.</p>
|
| Citation |
Inorganic Chemistry, 60(23), p. 18296-18306
|
| ISSN |
1520-510X
0020-1669
|
| Pubmed ID |
34787414
|
| Link | |
| Language |
en
|
| Publisher |
American Chemical Society
|
| Rights |
Attribution 4.0 International
|
| Title |
Extensive Redox Non-Innocence in Iron Bipyridine-Diimine Complexes: a Combined Spectroscopic and Computational Study
|
| Type of document |
Journal Article
|
| Entity Type |
Publication
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