Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/3658
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dc.contributor.authorPham, Thi Thuy Binhen
dc.contributor.authorFellows, Christopheren
dc.contributor.authorGilbert, Robert Gen
dc.date.accessioned2009-12-08T10:30:00Z
dc.date.issued2004en
dc.identifier.citationJournal of Polymer Science: Part A - Polymer Chemistry, 42(14), p. 3404-3416en
dc.identifier.issn1099-0518en
dc.identifier.issn0887-624Xen
dc.identifier.urihttps://hdl.handle.net/1959.11/3658en
dc.description.abstractHomogeneous copolymer latex particles of dodecyl methacrylate (DMA) and low-molecular-weight hydroxy-terminated polybutadiene (HTPB) oligomers were prepared by free-radical polymerization using miniemulsion methods. Rate data and latex characteristics were consistent with the classical miniemulsion mechanism where nucleation of monomer droplets is the predominant pathway of particle formation. There is essentially no particle formation by secondary nucleation in the water phase. Characterization of the copolymer latex particles using transmission electron microscopy and modulated differential scanning calorimetry suggested that there is a significant amount of grafted poly(DMA)/HTPB polymer contributing to the miscibility of the HTPB and poly(DMA) phases. Particles were more homogeneous at increased HTPB composition, of relatively narrow polydispersity, and could be prepared reproducibly using a number of different initiation systems. The observed trends can all be rationalized in terms of conventional understanding of miniemulsion polymerization systems.en
dc.languageenen
dc.publisherJohn Wiley & Sons Incen
dc.relation.ispartofJournal of Polymer Science: Part A - Polymer Chemistryen
dc.titleGrafting of dodecyl methacrylate onto hydroxylated polybutadiene by miniemulsion polymerizationen
dc.typeJournal Articleen
dc.identifier.doi10.1002/pola.20131en
dc.subject.keywordsSynthesis of Materialsen
local.contributor.firstnameThi Thuy Binhen
local.contributor.firstnameChristopheren
local.contributor.firstnameRobert Gen
local.subject.for2008030306 Synthesis of Materialsen
local.subject.seo2008860608 Rubber and Synthetic Resinsen
local.profile.schoolSchool of Science and Technologyen
local.profile.emailcfellows@une.edu.auen
local.output.categoryC1en
local.record.placeauen
local.record.institutionUniversity of New Englanden
local.identifier.epublicationsrecordpes:7147en
local.publisher.placeHoboken, United States of Americaen
local.format.startpage3404en
local.format.endpage3416en
local.peerreviewedYesen
local.identifier.volume42en
local.identifier.issue14en
local.contributor.lastnamePhamen
local.contributor.lastnameFellowsen
local.contributor.lastnameGilberten
dc.identifier.staffune-id:cfellowsen
local.profile.orcid0000-0002-8976-8651en
local.profile.roleauthoren
local.profile.roleauthoren
local.profile.roleauthoren
local.identifier.unepublicationidune:3748en
dc.identifier.academiclevelAcademicen
local.title.maintitleGrafting of dodecyl methacrylate onto hydroxylated polybutadiene by miniemulsion polymerizationen
local.output.categorydescriptionC1 Refereed Article in a Scholarly Journalen
local.description.statisticsepubsVisitors: 174<br />Views: 174<br />Downloads: 0en
local.search.authorPham, Thi Thuy Binhen
local.search.authorFellows, Christopheren
local.search.authorGilbert, Robert Gen
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School of Science and Technology
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