Bio-Based Chiral Amines via Aza-Michael Additions to (-)-Levoglucosenone Under Aqueous Conditions

Title
Bio-Based Chiral Amines via Aza-Michael Additions to (-)-Levoglucosenone Under Aqueous Conditions
Publication Date
2018-05-08
Author(s)
Kim, Shi-Wei
Ledingham, Edward T
Kudo, Shinji
Greatrex, Ben W
( author )
OrcID: https://orcid.org/0000-0002-0356-4966
Email: bgreatre@une.edu.au
UNE Id une-id:bgreatre
Sperry, Jonathan
Type of document
Journal Article
Language
en
Entity Type
Publication
Publisher
Wiley-VCH Verlag GmbH & Co KGaA
Place of publication
Germany
DOI
10.1002/ejoc.201800388
UNE publication id
une:1959.11/26830
Abstract
Chiral amines are highly coveted within the fine‐chemical industry and sustainable synthetic methodologies for their production are of great value. By harnessing the chirality present in cellulose‐derived (–)‐levoglucosenone (LGO), several bio‐based sp³‐rich amines containing up to four chiral centres have been readily prepared under aqueous conditions without using any catalysts, ligands, auxiliaries or resolutions.
Link
Citation
European Journal of Organic Chemistry, 2018(17), p. 2028-2038
ISSN
1099-0690
1434-193X
Start page
2028
End page
2038

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