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https://hdl.handle.net/1959.11/20693
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DC Field | Value | Language |
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dc.contributor.author | Hu, Yingxue | en |
dc.contributor.author | Marlow, Joshua B | en |
dc.contributor.author | Ramanathan, Rajesh | en |
dc.contributor.author | Zou, Wenyue | en |
dc.contributor.author | Tiew, Hui Geok | en |
dc.contributor.author | Pottage, Matthew J | en |
dc.contributor.author | Bansal, Vipul | en |
dc.contributor.author | Tabor, Rico F | en |
dc.contributor.author | Wilkinson, Brendan | en |
dc.date.accessioned | 2017-05-07T16:31:00Z | - |
dc.date.issued | 2015 | - |
dc.identifier.citation | Australian Journal of Chemistry, 68(12), p. 1880-1884 | en |
dc.identifier.issn | 1445-0038 | en |
dc.identifier.issn | 0004-9425 | en |
dc.identifier.uri | https://hdl.handle.net/1959.11/20693 | - |
dc.description.abstract | We describe the parallel synthesis, photocontrollable surface tension, and antibacterial performance of a new class of carbohydrate fluorosurfactant. Novel fluorosurfactants comprised a mono- or disaccharide head group linked to an azobenzene unit that was variably substituted with a trifluoromethyl group. Fluorosurfactants were rapidly assembled using the venerable CuI-catalysed azide-alkyne cycloaddition reaction and exhibited light-addressable surface activity, excellent water solubility, and selective antibacterial activity against Gram-positive 'Staphylococcus aureus'. Notably, the physicochemical and biological activity of these novel materials was heavily dependent on the nature of the head group and the position of the trifluoromethyl substituent on the azobenzene ring. The UV-adapted 'cis'-isomer of fluorosurfactants displayed good thermal stability at ambient temperature, with little reversion to the stable 'trans' isomer after 16 h. These novel, light-responsive materials should find broad interest in a range of biomedical and technological fields, including drug and gene delivery, self-cleaning oleophobic surfaces, and antibacterial coatings for medical devices. | en |
dc.language | en | en |
dc.publisher | CSIRO Publishing | en |
dc.relation.ispartof | Australian Journal of Chemistry | en |
dc.title | Synthesis and Properties of Photoswitchable Carbohydrate Fluorosurfactants | en |
dc.type | Journal Article | en |
dc.identifier.doi | 10.1071/CH15434 | en |
dc.subject.keywords | Colloid and Surface Chemistry | en |
dc.subject.keywords | Biologically Active Molecules | en |
dc.subject.keywords | Organic Chemical Synthesis | en |
local.contributor.firstname | Yingxue | en |
local.contributor.firstname | Joshua B | en |
local.contributor.firstname | Rajesh | en |
local.contributor.firstname | Wenyue | en |
local.contributor.firstname | Hui Geok | en |
local.contributor.firstname | Matthew J | en |
local.contributor.firstname | Vipul | en |
local.contributor.firstname | Rico F | en |
local.contributor.firstname | Brendan | en |
local.subject.for2008 | 030503 Organic Chemical Synthesis | en |
local.subject.for2008 | 030603 Colloid and Surface Chemistry | en |
local.subject.for2008 | 030401 Biologically Active Molecules | en |
local.subject.seo2008 | 929999 Health not elsewhere classified | en |
local.subject.seo2008 | 970103 Expanding Knowledge in the Chemical Sciences | en |
local.profile.school | School of Science and Technology | en |
local.profile.email | bwilkin7@une.edu.au | en |
local.output.category | C1 | en |
local.record.place | au | en |
local.record.institution | University of New England | en |
local.identifier.epublicationsrecord | une-20170323-104816 | en |
local.publisher.place | Australia | en |
local.format.startpage | 1880 | en |
local.format.endpage | 1884 | en |
local.identifier.scopusid | 84950289844 | en |
local.peerreviewed | Yes | en |
local.identifier.volume | 68 | en |
local.identifier.issue | 12 | en |
local.contributor.lastname | Hu | en |
local.contributor.lastname | Marlow | en |
local.contributor.lastname | Ramanathan | en |
local.contributor.lastname | Zou | en |
local.contributor.lastname | Tiew | en |
local.contributor.lastname | Pottage | en |
local.contributor.lastname | Bansal | en |
local.contributor.lastname | Tabor | en |
local.contributor.lastname | Wilkinson | en |
dc.identifier.staff | une-id:bwilkin7 | en |
local.profile.orcid | 0000-0003-1866-6540 | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.identifier.unepublicationid | une:20886 | en |
dc.identifier.academiclevel | Academic | en |
local.title.maintitle | Synthesis and Properties of Photoswitchable Carbohydrate Fluorosurfactants | en |
local.output.categorydescription | C1 Refereed Article in a Scholarly Journal | en |
local.relation.grantdescription | ARC/DE130101673 | en |
local.search.author | Hu, Yingxue | en |
local.search.author | Marlow, Joshua B | en |
local.search.author | Ramanathan, Rajesh | en |
local.search.author | Zou, Wenyue | en |
local.search.author | Tiew, Hui Geok | en |
local.search.author | Pottage, Matthew J | en |
local.search.author | Bansal, Vipul | en |
local.search.author | Tabor, Rico F | en |
local.search.author | Wilkinson, Brendan | en |
local.uneassociation | Unknown | en |
local.year.published | 2015 | en |
local.subject.for2020 | 340503 Organic chemical synthesis | en |
local.subject.for2020 | 340603 Colloid and surface chemistry | en |
local.subject.for2020 | 340401 Biologically active molecules | en |
local.subject.seo2020 | 280105 Expanding knowledge in the chemical sciences | en |
Appears in Collections: | Journal Article |
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