Please use this identifier to cite or link to this item:
Title: Triphenylphosphine-Induced Ring Contraction of 1,2-Dioxines
Contributor(s): Greatrex, Ben  (author)orcid ; Taylor, Dennis K (author)
Publication Date: 2004
DOI: 10.1021/jo030330c
Handle Link:
Abstract: Triphenylphosphine inserts into the peroxide bond of 1,2-dioxines, initiating ring contraction with loss of triphenylphosphine oxide. This process yields dihydrofuran oxides in 54-97% yield from oxirenyl[2,3-c][1,2]dioxines and dihydrofurans from 3,6-dihydro-1,2-dioxines with inversion of stereochemistry at either the 2 or 5 position in the furan product.
Publication Type: Journal Article
Source of Publication: Journal of Organic Chemistry, 69(7), p. 2577-2579
Publisher: American Chemical Society
Place of Publication: United States of America
ISSN: 0022-3263
Field of Research (FoR) 2008: 030599 Organic Chemistry not elsewhere classified
030503 Organic Chemical Synthesis
Socio-Economic Objective (SEO) 2008: 970103 Expanding Knowledge in the Chemical Sciences
Peer Reviewed: Yes
HERDC Category Description: C1 Refereed Article in a Scholarly Journal
Statistics to Oct 2018: Visitors: 161
Views: 164
Downloads: 0
Appears in Collections:Journal Article
School of Rural Medicine

Files in This Item:
2 files
File Description SizeFormat 
Show full item record


checked on Jun 14, 2021

Page view(s)

checked on May 3, 2019
Google Media

Google ScholarTM



Items in Research UNE are protected by copyright, with all rights reserved, unless otherwise indicated.