Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/15520
Title: A Domino Ring-Opening/Epoxidation of 1,2-Dioxines
Contributor(s): Greatrex, Ben  (author)orcid ; Taylor, Dennis K (author); Tiekink, Edward R T (author)
Publication Date: 2004
DOI: 10.1021/jo030330c
Handle Link: https://hdl.handle.net/1959.11/15520
Abstract: When allowed to react with alkaline hydrogen peroxide, monocyclic 1,2-dioxines ring-open to their isomeric 'y'-hydroxyenone intermediates which are rapidly epoxidized to afford 'trans'-4-hydroxy-2,3-epoxyketones in 21-81% yield. In the case of 'meso'-1,2-dioxines, Co(II) complex catalyzed asymmetric ring-opening of the 1,2-dioxine may be employed to furnish enantioenriched epoxides.
Publication Type: Journal Article
Source of Publication: Journal of Organic Chemistry, 69(7), p. 2580-2583
Publisher: American Chemical Society
Place of Publication: United States of America
ISSN: 1520-6904
0022-3263
Field of Research (FOR): 030503 Organic Chemical Synthesis
030599 Organic Chemistry not elsewhere classified
Socio-Economic Outcome Codes: 970103 Expanding Knowledge in the Chemical Sciences
Peer Reviewed: Yes
HERDC Category Description: C1 Refereed Article in a Scholarly Journal
Statistics to Oct 2018: Visitors: 237
Views: 250
Downloads: 0
Appears in Collections:Journal Article
School of Rural Medicine

Files in This Item:
2 files
File Description SizeFormat 
Show full item record

SCOPUSTM   
Citations

16
checked on Nov 26, 2018

Page view(s)

126
checked on May 3, 2019
Google Media

Google ScholarTM

Check

Altmetric


Items in Research UNE are protected by copyright, with all rights reserved, unless otherwise indicated.