Please use this identifier to cite or link to this item: https://hdl.handle.net/1959.11/15067
Title: Practical Evaluation of Compact Fluorescent Lamps for Dye-Sensitized Photooxidation Reactions
Contributor(s): Stockton, Kieran (author); May, Joseph (author); Taylor, Dennis (author); Greatrex, Ben  (author)orcid 
Publication Date: 2014
DOI: 10.1055/s-0033-1340976
Handle Link: https://hdl.handle.net/1959.11/15067
Abstract: Energy-efficient compact fluorescent lamps (CFL) have been evaluated as a light source for the sensitized generation of singlet oxygen used in the oxidation of 1,3-butadienes and furfural derivatives using a range of dyes including rose bengal, methylene blue, and tetraphenylporphyrin. An ambient temperature water jacket was sufficient to cool reaction mixtures due to the low heat output of lamps and the reaction rates using 110 W of CFL were slower but comparable to those obtained using a 500 W tungsten halogen lamp. The conditions were applied to the photooxidation of a series of furan aldehydes and 1,3-butadienes to give products in good yield in 4-96 hours.
Publication Type: Journal Article
Source of Publication: Synlett, 25(8), p. 1168-1172
Publisher: Georg Thieme Verlag
Place of Publication: Germany
ISSN: 1437-2096
0936-5214
Field of Research (FOR): 030504 Organic Green Chemistry
030503 Organic Chemical Synthesis
030599 Organic Chemistry not elsewhere classified
Socio-Economic Objective (SEO): 970103 Expanding Knowledge in the Chemical Sciences
Peer Reviewed: Yes
HERDC Category Description: C1 Refereed Article in a Scholarly Journal
Statistics to Oct 2018: Visitors: 397
Views: 436
Downloads: 0
Appears in Collections:Journal Article

Files in This Item:
3 files
File Description SizeFormat 
Show full item record

SCOPUSTM   
Citations

4
checked on Nov 30, 2018

Page view(s)

46
checked on May 2, 2019
Google Media

Google ScholarTM

Check

Altmetric


Items in Research UNE are protected by copyright, with all rights reserved, unless otherwise indicated.