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https://hdl.handle.net/1959.11/1436
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DC Field | Value | Language |
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dc.contributor.author | Gunter, Maxwell John | en |
dc.contributor.author | Farquhar, Sandra | en |
dc.contributor.author | Mullen, Kathleen | en |
dc.date.accessioned | 2009-05-04T11:56:00Z | - |
dc.date.issued | 2004 | - |
dc.identifier.citation | New Journal of Chemistry, 28(12), p. 1443-1449 | en |
dc.identifier.issn | 1369-9261 | en |
dc.identifier.issn | 1144-0546 | en |
dc.identifier.uri | https://hdl.handle.net/1959.11/1436 | - |
dc.description.abstract | The synthesis of a porphyrin with an over-arching strap incorporating an isophthalamide unit produced both a porphyrin monomer with a potentially H-bonding receptor site, and a [2]catenane. Although both compounds exhibit fluxional behaviour, ¹H NMR and MS data was used to distinguish them, and was interpreted in terms of the dynamics of each system. The self-complementarity of the isophthalamide unit provides an ideal building block for assembling [2]pseudorotaxanes with similarly functionalised threads. This was illustrated by the self-assembly of a ruthenium–porphyrin stoppered rotaxane under thermodynamically controlled conditions, by simple mixing of the strapped porphyrin, a complementary thread unit containing an isophthalamide central unit and pyridine-attached ends, and a ruthenium carbonyl porphyrin. The strapped porphyrin was also shown to act as a receptor for chloride ion, and its binding ability with other H-bonding isophthalamide guests was found to be modulated by the presence of chloride ion. Chloride complexation was observed in both metallated and free base porphyrin monomers as well as the rotaxanes counterparts, but no anion binding was observed for the catenane. | en |
dc.language | en | en |
dc.publisher | Royal Society of Chemistry | en |
dc.relation.ispartof | New Journal of Chemistry | en |
dc.title | Amide-appended porphyrins as scaffolds for catenanes, rotaxanes and anion receptors | en |
dc.type | Journal Article | en |
dc.identifier.doi | 10.1039/b411583j | en |
dc.subject.keywords | Nanochemistry and Supramolecular Chemistry | en |
local.contributor.firstname | Maxwell John | en |
local.contributor.firstname | Sandra | en |
local.contributor.firstname | Kathleen | en |
local.subject.for2008 | 030302 Nanochemistry and Supramolecular Chemistry | en |
local.subject.seo | 780103 Chemical sciences | en |
local.profile.school | School of Science and Technology | en |
local.profile.school | School of Science and Technology | en |
local.profile.school | School of Science and Technology | en |
local.profile.email | mgunter4@une.edu.au | en |
local.profile.email | kmullen2@une.edu.au | en |
local.output.category | C1 | en |
local.record.place | au | en |
local.record.institution | University of New England | en |
local.identifier.epublicationsrecord | pes:1377 | en |
local.publisher.place | United Kingdom | en |
local.format.startpage | 1443 | en |
local.format.endpage | 1449 | en |
local.identifier.scopusid | 11244324867 | en |
local.peerreviewed | Yes | en |
local.identifier.volume | 28 | en |
local.identifier.issue | 12 | en |
local.contributor.lastname | Gunter | en |
local.contributor.lastname | Farquhar | en |
local.contributor.lastname | Mullen | en |
dc.identifier.staff | une-id:mgunter2 | en |
dc.identifier.staff | une-id:sfarquha | en |
dc.identifier.staff | une-id:kmullen2 | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.identifier.unepublicationid | une:1469 | en |
dc.identifier.academiclevel | Academic | en |
dc.identifier.academiclevel | Academic | en |
local.title.maintitle | Amide-appended porphyrins as scaffolds for catenanes, rotaxanes and anion receptors | en |
local.output.categorydescription | C1 Refereed Article in a Scholarly Journal | en |
local.search.author | Gunter, Maxwell John | en |
local.search.author | Farquhar, Sandra | en |
local.search.author | Mullen, Kathleen | en |
local.uneassociation | Unknown | en |
local.identifier.wosid | 000225620000011 | en |
local.year.published | 2004 | en |
Appears in Collections: | Journal Article |
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