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https://hdl.handle.net/1959.11/1327
Title: | Gel-phase HR-MAS ¹H NMR spectroscopy as a probe for solid-tethered diimide rotaxanes and catenanes | Contributor(s): | Johnstone, Ken (author); Bampos, N (author); Sanders, JKM (author); Gunter, Maxwell John (author) | Publication Date: | 2006 | DOI: | 10.1039/b602555b | Handle Link: | https://hdl.handle.net/1959.11/1327 | Abstract: | The design and kinetically-controlled construction of a series of solid-tethered supramolecular systems utilising crown ether–naphthalene diimide host–guest chemistry are described.Functionalised polystyrene beads (ArgoGel-OH™) were utilised as the gel-phase solid support for the assembly of an appended diimide-crown catenane, and for a porphyrin-stoppered diimidecrown rotaxane. The structures of the resulting solid-tethered systems were probed using gelphase high-resolution magic-angle spinning (HR-MAS) ¹H NMR spectroscopy. The advantages of using this spectroscopic tool in conjunction with optical microscopy to probe solid-tethered supramolecular systems are discussed. | Publication Type: | Journal Article | Source of Publication: | New Journal of Chemistry, v.30, p. 861-867 | Publisher: | Royal Society of Chemistry | Place of Publication: | United Kingdom | ISSN: | 1369-9261 1144-0546 |
Fields of Research (FoR) 2008: | 030302 Nanochemistry and Supramolecular Chemistry | Peer Reviewed: | Yes | HERDC Category Description: | C1 Refereed Article in a Scholarly Journal |
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Appears in Collections: | Journal Article |
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