Please use this identifier to cite or link to this item:
https://hdl.handle.net/1959.11/1325
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DC Field | Value | Language |
---|---|---|
dc.contributor.author | Gaynor, Shaun Patrick | en |
dc.contributor.author | Gunter, Maxwell John | en |
dc.contributor.author | Johnston, MR | en |
dc.contributor.author | Warrener, RN | en |
dc.date.accessioned | 2009-05-01T13:46:00Z | - |
dc.date.issued | 2006 | - |
dc.identifier.citation | Organic & Biomolecular Chemistry, v.4, p. 2253-2266 | en |
dc.identifier.issn | 1477-0539 | en |
dc.identifier.issn | 1477-0520 | en |
dc.identifier.uri | https://hdl.handle.net/1959.11/1325 | - |
dc.description.abstract | The synthesis of a series of open U-shaped 'bis'-porphyrin cavity molecules is described, with bridged bicyclic backbones to confer rigidity, and a pendant substituted aromatic probe unit suspended on the inside of the cavity. The dimensions and flexibility of the 'bis'-zincporphyrin cavity were probed using several different techniques. Initially the molecular ruler concept was employed, using flexible bidentate ligands as guests with a range of possible linear dimensions. Secondly, NMR methods were employed with rigid bidentate ligand guests of fixed lengths, and thirdly diffusion based NMR methods were utilised. The range of inter-porphyrin distances estimated by these methods suggests that these types of open-cavity systems have a surprising degree of flexibility. | en |
dc.language | en | en |
dc.publisher | Royal Society of Chemistry | en |
dc.relation.ispartof | Organic & Biomolecular Chemistry | en |
dc.title | Probing the dimensions of semi-rigid inner functionalised U-shaped 'bis'-porphyrin cavities | en |
dc.type | Journal Article | en |
dc.identifier.doi | 10.1039/b601417h | en |
dc.subject.keywords | Nanochemistry and Supramolecular Chemistry | en |
local.contributor.firstname | Shaun Patrick | en |
local.contributor.firstname | Maxwell John | en |
local.contributor.firstname | MR | en |
local.contributor.firstname | RN | en |
local.subject.for2008 | 030302 Nanochemistry and Supramolecular Chemistry | en |
local.subject.seo | 780103 Chemical sciences | en |
local.profile.school | School of Science and Technology | en |
local.profile.school | School of Science and Technology | en |
local.profile.email | mgunter4@une.edu.au | en |
local.output.category | C1 | en |
local.record.place | au | en |
local.record.institution | University of New England | en |
local.identifier.epublicationsrecord | pes:3205 | en |
local.publisher.place | United Kingdom | en |
local.format.startpage | 2253 | en |
local.format.endpage | 2266 | en |
local.identifier.scopusid | 33744811477 | en |
local.peerreviewed | Yes | en |
local.identifier.volume | 4 | en |
local.contributor.lastname | Gaynor | en |
local.contributor.lastname | Gunter | en |
local.contributor.lastname | Johnston | en |
local.contributor.lastname | Warrener | en |
dc.identifier.staff | une-id:sgaynor3 | en |
dc.identifier.staff | une-id:mgunter2 | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.profile.role | author | en |
local.identifier.unepublicationid | une:1354 | en |
dc.identifier.academiclevel | Academic | en |
local.title.maintitle | Probing the dimensions of semi-rigid inner functionalised U-shaped 'bis'-porphyrin cavities | en |
local.output.categorydescription | C1 Refereed Article in a Scholarly Journal | en |
local.search.author | Gaynor, Shaun Patrick | en |
local.search.author | Gunter, Maxwell John | en |
local.search.author | Johnston, MR | en |
local.search.author | Warrener, RN | en |
local.uneassociation | Unknown | en |
local.identifier.wosid | 000237907500019 | en |
local.year.published | 2006 | en |
Appears in Collections: | Journal Article |
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