Blanch, Ewan; Keir, Roland; Ritchie, Geoffrey

Rayleigh Depolarization Ratios, Kerr Effects, Polarizabilities, and Hyperpolarizabilities of CH₃Br, CH₂Br₂, CHBr₃ and CBr₄.: Comparison of Experimental and ab Initio Calculated Polarizabilities

Name: Rayleigh Depolarization Ratios, Kerr Effects, Polarizabilities, and Hyperpolarizabilities of CH₃Br, CH₂Br₂, CHBr₃ and CBr₄.: Comparison of Experimental and ab Initio Calculated Polarizabilities
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Author(s)	Blanch, Ewan Keir, Roland Ritchie, Geoffrey
Publication Date	2002
Abstract	Improved equipment has been used to record the vapor-phase Rayleigh depolarization ratios and electrooptical Kerr effects of CH₃Br, CH₂Br₂, CHBr₃, and CBr₄ at elevated temperatures. The measurements yield experimental values of the anisotropic polarizabilities and the Kerr hyperpolarizabilities of these molecules. As well, Dougherty and Spackman's HUZ-SV(+sd+sp) basis set has been used to compute SCF and MP2-level polarizabilities, and these are compared with the experimental results.
Citation	The Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory, 106(16), p. 4257-4262
ISSN	1520-5215 1089-5639
Link	https://hdl.handle.net/1959.11/1435
Publisher	American Chemical Society
Title	Rayleigh Depolarization Ratios, Kerr Effects, Polarizabilities, and Hyperpolarizabilities of CH₃Br, CH₂Br₂, CHBr₃ and CBr₄.: Comparison of Experimental and ab Initio Calculated Polarizabilities
Type of document	Journal Article
Entity Type	Publication

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