4-Hydroxymethyl-1-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-1,2,3-triazole

Author(s)
Wilkinson, Brendan
Bornaghi, Laurent F
Houston, Todd A
Poulsen, Sally-Ann
White, Alan R
Publication Date
2006
Abstract
The structure of the title compound, C₁₇H₂₃N₃O₁₀, (2), has been determined as part of our investigation into the synthetic utility of the glucosyl triazole unit in carbohydrate chemistry. Compound (2) was synthesized by the 1,3-dipolar cyclo­addition reaction of propargyl alcohol with 2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl azide under conditions which afforded (2) exclusively with complete retention of anomeric stereochemistry. The six-membered carbohydrate ring adopts a chair conformation. The non-H substituents are located in equatorial positions.
Citation
Acta crystallographica. Section E, 62(11), p. o5065-o5067
ISSN
2056-9890
1600-5368
Link
https://hdl.handle.net/1959.11/22905
Language
en
Publisher
International Union of Crystallography (IUCr)
Title
4-Hydroxymethyl-1-(2,3,4,6-tetra-O-acetyl-β-D-glucopyranosyl)-1,2,3-triazole
Type of document
Journal Article
Entity Type
Publication

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